On a ruler's tombstone, it is said that one sixth of his life was spent in childhood and one twelfth as a teenager. One seventh of his life passed between the time he became an adult and the time he married; five years later, his son was born. Alas, the son died four years before he did. He lived to be twice as old as his son did. How old did the ruler live to be ?
The order of basicity in ammonia is different in gaseous phases vs. aqueous phases due to hydrogen bonding.
So in gaseous phases it's the well known: 3' > 2' > 1'> NH3. Just so we're on the same page, this is due to the inductive effect of electron donating alkyl groups--they destabilize the lone pair on nitrogen atom, making nitrogen more basic.
But in aqueous phase, the order is slightly different: 2'> 1'> 3' > NH3.
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