Molecular compounds are those with covalent bonds between the elements and those elements are typically non metals.
Here in the given options, Ar is an element. NaI has an ionic bond. Hence, N2O4 has a covalent bond between the two non metals and is a molecular compound.
Latitude of place is indicative of its temperature. In geography, latitude is a geographic coordinate that specifies the north–south position of a point on the Earth's surface. Latitude is an angle which ranges from 0° at the Equator to 90° at the poles.