Questions

The given compound is NaHCO3 Sodium bicarbonate which is commonly known as Baking soda.

Oxidation numbers are the charges on ions. When a neutral atom loses electrons it becomes positively charged. When a neutral atom gains electrons it becomes negatively charged.

Here the C represents the oxidation state of carbon in this compound. Compounds are electrically neutral, which is why we set the sum of the oxidation states equal to zero.

Sodium has a +1 oxidation state. Hydrogen has a +1 oxidation state. Oxygen has a -2 oxidation state. There are three oxygen atoms, which means the total oxidation state provided by both oxygen ions is -6. Adding up these oxidation states we get:

1 + 1 + (-6) + C = 0

-4 + C = 0

=> C = 4

This means the oxidation state of carbon in this compound is +4.

From the hints,

Only two options for 1st and 2nd digits => 4,2 and 9,3 since it is single digits

Sum of second and third digit  = 10 

If 2 => 3rd digit = 8

If 3 => 3rd digit = 7

4th digit = 2nd digit + 1 => (2+1 =3) or (3+1 = 4)

Sum of all digits = 30

Let 5th digit be x

=> 1st possibility = 4 + 2 + 8 + 3 + x = 30 => x = 13 (Not possible since it has 2 digits)

=> 2nd possibility = 9 + 3 + 7 + 4 + x = 30 => x = 7

Therefore, the PIN is 93747 

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