Questions

The order of basicity in ammonia is different in gaseous phases vs. aqueous phases due to hydrogen bonding.

So in gaseous phases it's the well known: 3' > 2' > 1'> NH3. Just so we're on the same page, this is due to the inductive effect of electron donating alkyl groups--they destabilize the lone pair on nitrogen atom, making nitrogen more basic.

But in aqueous phase, the order is slightly different: 2'> 1'> 3' > NH3.

If as a business, you buy goods or services on credit from a supplier (accounts payable) then the supplier will supply the goods and business will incur a liability to the supplier for that amount, but no cash will change hands at that stage.

Some of those shop keepers allowed regular "trustworthy" customers to purchase items without having the full payment.

Hence, Buying on credit means that no actual money has changed hands.

The provisional geographical area of india as on 31st March 1982, given by survey of india, is 3287,263 sq km. which includes 78,111 sq km under occupation by pakistan, 5180 sqkm given by pakistan to china and 37,555 sq km under occupation of china.