Questions

From the hints,

Only two options for 1st and 2nd digits => 4,2 and 9,3 since it is single digits

Sum of second and third digit  = 10 

If 2 => 3rd digit = 8

If 3 => 3rd digit = 7

4th digit = 2nd digit + 1 => (2+1 =3) or (3+1 = 4)

Sum of all digits = 30

Let 5th digit be x

=> 1st possibility = 4 + 2 + 8 + 3 + x = 30 => x = 13 (Not possible since it has 2 digits)

=> 2nd possibility = 9 + 3 + 7 + 4 + x = 30 => x = 7

Therefore, the PIN is 93747 

Chromium is the chemical element that is used as a shiny metal on the automobile bodies especially for trim.

Facilitate means assist someone in their progress or work. Here Help is the only word which is similar in meaning with facilitate. Halt and check are antonyms i.e opposite in meaning of facilitate. 

Hence, facilitate is similar in meaning to help.

Demat means Dematerialisation of share, in simple it is an account with which a person can trade in security market without which a person cannot buy or sell any share in security market. 

In 1814, George Stephenson developed steam engine to haul coal from mines to ports by railways. In 1830, the first railway train began to carry passengers and freight from Liverpool to Manchester.