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Q:

Among the following the maximum covalent character is shown by the compound

(1) $M g C l_{2}$

(2) $F e C l_{2}$

(3) $S n C l_{2}$

(4) $A l C l_{3}$

A) Option 1	B) Option 2
C) Option 3	D) Option 4

Answer & Explanation Answer: D) Option 4

Explanation:

According to Fajans rule, cation with greater charge and smaller size favours covalency.

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Q:

Trichloroacetaldehyde was subject to Cannizzaro's reaction by using NaOH. The mixture of the products contains sodium trichloroacetate and another compound. The other compound is :

A) Chloroform	B) 2, 2, 2-Trichloroethanol
C) Trichloromethanol	D) 2, 2, 2-Trichloropropanol

Answer & Explanation Answer: B) 2, 2, 2-Trichloroethanol

Explanation:

$\begin{matrix} C l \\ | \\ C l & - & C & - & C H O \\ | \\ C l \end{matrix}$ $\to_{C a n n i z z a r o' s R e a c t i o n}^{N a O H}$ $\begin{matrix} C l \\ | \\ C l & - & C & - & C O O N a \\ | \\ C l \end{matrix}$ $+$ $\begin{matrix} C l \\ | \\ C l & - & C & - & C H_{2} \\ | 2 & 1 \\ C l \end{matrix}$ $- O H$

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Q:

Silver Mirror test is given by which one of the following compounds?

1. Benzophenone

2. Acetaldehyde

3. Acetone

4. Formaldehyde

A) Only 1	B) Only 2
C) 1 and 3	D) 2 and 4

Answer & Explanation Answer: D) 2 and 4

Explanation:

Both Formaldehyde and Acetaldehyde will give this test

$H C H O \overset{[A g (N H_{3})_{2}^{+}]}{\to} \overset{A g}{S i l v e r m i r r o r} + O r g a n i c c o m p o u n d$

$C H_{3} - C H O \overset{[A g (N H_{3})_{2}^{+}]}{\to} \underset{S i l v e r m i r r o r}{A g} + O r g a n i c c o m p o u n d$

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Q:

The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a volume of 10 $d m^{3}$ at 27°C is to a volume of 100 $d m^{3}$

A) 42.3 J/ mole / K	B) 38.3 J/ mole / K
C) 35.8 J/ mole / K	D) 32.3 J/ mole / K

Answer & Explanation Answer: B) 38.3 J/ mole / K

Explanation:

$∆ s = n R \ln \frac{v 2}{v 1}$

$= 2.303 n R \log \frac{v 2}{v 1}$ = $2.303 \times 2 \times 8.314 \times \log (\frac{100}{10})$ = $38.3 J$ $m o l^{- 1}$ $k^{- 1}$

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Q:

Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which should be added to 4 kg of water to prevent it from freezing at –6°C will be: (Kf for water = 1.86 Kg/mol and molar mass of ethylene glycol = 62 kg/mol)

A) 204.60 g	B) 304.30 g
C) 804.32 g	D) 400.00 g

Answer & Explanation Answer: C) 804.32 g

Explanation:

$∆ T_{f} = k_{f} . m$

for ethylene glycol in aq. solution

$∆ T_{f} = k_{f} \frac{w}{m o l . w t} \times \frac{1000}{w t . o f s o l v e n t} 6 = \frac{1.86 x w x 1000}{62 x 4000}$

=> w = 800 g

So, the weight of solute should be more than 800 g.

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Q:

Which is the largest epic in world ?

Answer

Mahabharat

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Subject: Longest, Shortest, Deepest

Q:

Which is Highest Gallantry Award in India ?

Answer

Paramveer Chakra

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Subject: Longest, Shortest, Deepest

Q:

Which is the Hottest Place in the World ?

Answer

Azizia (Libya,Africa) 136 F

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Subject: Longest, Shortest, Deepest

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